Research
carbon chemistry, carbon chemistry, heterogeneous catalysis Ismagilov is a world-renowned scientist in the field of carbon chemistry, carbon chemistry and heterogeneous catalysis. Under his leadership, fundamental studies of the structure of coals were carried out by modern physical and chemical methods, scientific foundations of pyrolysis and coal gasification, obtaining individual products of carbon chemistry and coke chemistry and their methods were developed clean-up, established patterns of polyaromatic hydrocarbons in the range of the metamorphism of coals. Scientific foundations for chemical disposal of coal seam methane by partial oxidation, dimericization and catalytic dehydroaromatization of methane into benzene with pure hydrogen have been developed. A large amount of research is being carried out on the processing of coal resin, classification of furnaces and creation of binders for the anodium smelters of the aluminium industry, including the ecology of coal-processing, coking and coal-chemical industries Studies of a wide range of industrial samples of needle cokes from various foreign manufacturers by EPR spectroscopy, Raman spectroscopy, X-ray structural analysis (RSA) and scanning electronic methods have been carried out (SEM). The findings revealed a relationship between the properties of raw materials, production technology and structural parameters and the morphology of coke, which is necessary to determine the basic properties of coke and allows the selection of thermal modes to obtain high quality anisotropic needle cokes and then enter the organization of domestic production. For the first time, the reactions of oxidative transformation of fossil coals under the influence of laser radiation have been investigated. Experiments using a pulsed laser revealed the mechanism of thermal processes and ignition of coals including microsecond stages of heating the surface, the discharge of volatiles and their burning in the gas phase and the last stage of burning solid coke Balance. A large cycle of studies on the extraction of humic acids from brown and oxidized coals has been carried out, the compounds have been studied by a set of physical and chemical methods and methods of cooking gums for use as fertilizers have been developed. Together with specialists of agricultural institutes of the RAS, KemNIISH and IPA SB RAS carried out large-scale business experiments and production tests of the use of developed drugs, showed an increase in grain yields by 25-35% (wheat, oats). An experimental and industrial stand for the production of humates has been created, humin fertilizers have been developed and industrial tests have been initiated in the fields of Kuzbass agricultural enterprises. Methods of obtaining effective sorbents from fossil coals have been developed, and a modern large-scale stand for the production of carbon sorbents has been created. The research is being carried out as part of the FDC grant - the project aims to develop technological solutions for the production of efficient sorbents to purify water from various pollutants, including organic matter, petroleum products and heavy metals. The project will contribute to the development of sorbent production in Russia using its own raw materials, especially Kuzbass coals. This will solve the problem of cleaning mine and industrial wastewater in the coal-producing regions. Commercial organizations of Russia and Kazakhstan will be involved in the stage of industrial scaling of the technology. The results of the project are consistent with the concept of sustainable development and the creation of a high quality of life for people in the Russian Federation and the Republic of Kazakhstan. Much attention is paid to coal seam methane, methane, and mine methane disposal. As part of the 7th Framework European Programme - DEMCAMER - "Design and production of catalytic membrane reactors by developing new nanostructured catalytic and selective membrane materials" chocyal oxidation, dimmerization and aromatization of mine methane. A large cycle of research on catalytic membranes and microreactors has been performed. In the chemistry of carbon nano-materials a large cycle of work on the synthesis and research of the patterns of carbon nanofiber formation (UNV) has been carried out, and the structural, textural, adsorbtous and electrophysical properties of UNV have been studied in detail. A wide range of different carbon nanomaterials have been developed and developed: UNV, N-UNV, O-UNV, O,N-UNV, MUNT, N-MUNT, O-MUNT and O,N-MUNT. Original methods of modifying carbon nanomaterials have been developed to vary the heterotomus content and their condition: (1) the introduction of nitrogen atoms by direct embedding in the carbon structure during catalytic growth Carbon material (N-UNV and N-MUNT); (2) the introduction of oxygen atoms by oxidation of synthesized carbon nanomaterials with nitric acid (O-UNV, O,N-UNV and O-MUNT) and (3) the introduction of nitrogen atoms by post-processing of synthesized carbon material by nitrogen-containing bonds. The obtained data on the effects of the synthesis method on the physical and chemical properties of carbon nanomaterials (chemical composition, surface chemical composition, morphology, structure, defectivity, etc.) allow us to reasonably enter into the commercialization of methods fusion, including electrode materials for next-generation supercapacitors. In the field of heterogeneous catalysis under the direction of Ismagilov, the fundamental studies of the mechanism of a number of catalytic reactions by isotopic, kinetic and physical-chemical methods have been carried out. In 1982, he headed the department at the IC SB RAS on the topic of catalytic heat generators (CGT). On the basis of systematic fundamental research, technologies have been developed to synthesize super-strength spherical aluminium oxide carriers and CGT catalysts. During these years, under his leadership, a large amount of design work was carried out on the devices with a boiling layer of catalyst and on the development of specific technologies on a pilot-industrial scale. In the following years, these technologies evolved and some were brought to industrial use. In part of the fundamental works on catalysis under his leadership, pioneerstudies were carried out on the heterogenic-homogenized mechanism of catalytic reactions of oxidation of hydrocarbons and spirits by direct registration of radicals in the gas phase above Catalyst. For the first time, the accumulation of gas-phase radicals forming over the catalyst for these reactions was carried out using the original freezing technique directly in the EPR spectrometer resonator, which allowed to quantify the cynetics of these reactions and establish a detailed mechanism. Under his leadership, for the first time the stabilization of copper ions in the form of chain oxide (1-D) nanostructures in the channels of zeolite zSM-5 was found, the characteristic features of the electronic structure of copper-oxide clusters and oxidative-regenerative properties, well-founded methods of identification of detected structures. The study opens up new possibilities for the "soft" recovery technology of low-size oxide clusters to produce concentrated in the oxide matrix of metal nanoparticles with a wide range of catalytic and physics and chemical properties The localization of molybdenum nanoclusters in the highly ordered porous channels of the N-SM-5 zeolite with the size of the input windows of 0.6 nm has been investigated, and methods of synthesis of nanocatalysts for the conversion of methane into benzene and hydrogen have been developed. A method of preparation of nanoscale particles Pt and Pd on modified aluminium oxide and hexaaluminate materials has been developed. The role of nanoscale state of noble metals in the synergistic effect of Pd with marganalucic oxygen carrier in catalysts for automotive converters and catalytic chambers of combustion of gas turbines has been investigated. For the first time, the phenomenon of thermoactivation of uranium oxides when applied to aluminum oxide by impregnation or co-saturia of precursors of uranium and aluminum oxides has been established. When the piercing temperature rises to 1000oC, X-ray nano-sized uranium oxide is formed with a certain ratio of valence states, providing high catalytic activity. For the first time, the technology of industrial catalysts modified by nanostructures of depleted uranium oxides has been developed and patented. Scientific foundations have been developed, synthesized, researched and patented catalysts for ultra-deep hydro-cleaning of motor fuels from dibenzotyphenes, the high activity of which is provided by the optimal interaction of the ensemble of nanoparticles active component and media. Between 1975 and 1990. significant scientific activity of Ismagilov Z.R. was focused on applied work. The Ismagilov Z.R. has important results in interdisciplinary studies. Ash-gel methods for obtaining TiO2 nanodispersive particles with a size of 3-5 nm from organic and inorganic titanium compounds have been developed and methods of stabilizing them for nanobiomedical research have been developed. Together with colleagues from IHBM SB RAS, NSU, NSU and FIC Institute of Cytology and Genetics of SB RAS are creating and researching virus-specific reagents based on TiO2-oligonucleotide nanoparticles for directed splitting of the viral genome, the possibility of penetration into the cells of titanium dioxide nanoparticles and their conjurates with oligonucleotides has been investigated and, accordingly, their cytotoxicity and antiviral properties have been studied. Innovation: Ismagilov's scientific activity has a pronounced innovative character, he is the co-author of more than 150 author's certificates of the USSR, patents of the Russian Federation and foreign patents for inventions, with a noticeable number of practical implementations. The method of preparing and stabilizing platinum nanoparticles on carbon fibers for fuel cell catalysts is patented in Japan. He led the following projects: - Production of cellular block catalysts, 1990, Perm Production of Alcar-type alkylation catalyst, 1992, Aktau, Kazakhstan -demonstration plant for the disposal of liquid radioactive waste with a pseudo-liquid catalyst layer, 1994-1996, Novosibirsk - Production of catalytic heat generators, 1992-2010, Novosibirsk Catalysts and industrial technology of catalytic treatment of associated oil gases from hydrogen sulfide have been created. These catalysts and direct catalytic hydrogen sulfide oxidation technology are patented in leading Western countries and are implemented in industrial plants to clean associated oil gas from hydrogen sulfide: - . Bavlin oil field of Tatneft
- . Installation of the preparation of high-sulphur oil ltd. "Sheshmaoil"
- . Samp-Neftegaz Sarapalin oil field
- . Karachaganak oil and gas condensate field of Condensate (Republic of Kazakhstan)
- Currently, a hydrocracking disposal plant is being installed for Novatek-Ust-Luga LLC. The technology of direct catalytic oxidation of hydrogen sulfide was chosen by the results of the Closed Competition bidding as the most optimal compared to the technologies of competitors - WSA - Haldor Topsoe, THIOPA - UOP LLC, Shell Global Solutions B.V. and Paques B.V.
- Development of industrial hydrogen sulfide recycling plants has begun
- At Minibaevk GPP, Tatneft
- At the Koshehabli gas condensate field (Republic of Adygea), Yugazenerji Ltd.
In recent years, a large cycle of research on cleaning motor fuels from sulphurous compounds by catalytic oxidation has been carried out under a contract with Saudi Aramco. The successful results on catalysts and technology have resulted in more than 20 joint patents: the United States, China, Singapore, Korea and the European Patent Society. Experience of scientific and organizationalwork: Ismagilov has a lot of experience of scientific and organizational work: Head of the department in the IK SB RAS since 1983. 2010, Deputy Director General of Theatolik Since 1988. 1992. He is a member of the Presidium of SB RAS, the Scientific Council of the Russian Academy of Sciences on Catalysis, the Scientific Council of the Russian Academy of Sciences on the Chemistry of Fossil and Renewable Carbon-containing Raw Materials, the Bureau of SB RAS On Chemical Sciences. Ismagilov is the editor-in-chief of the journal Chemistry for Sustainable Development and a member of the editorial board of the magazine "Solid Fuel Chemistry" and several Russian and international magazines: - International Advisory Board, Encyclopedia of Catalysis, Editor-in-Chief Istvan T.Horvath (2002)
- Advisory Board, RSC Catalysis Book Series, Editor J James Spivey, 2008
- Applied Catalysis B Environmental (1998-2002)
- Eurasian Chemico -Technological Journal (since 2000)
- Burning and plasma chemistry (since 2003)
- Visiting Editor Catalysis Today v. 51, issues 3-4, 1999
- Visiting Editor Catalysis Today v. 144, issues 3-4, 2009
- Alternative Energy and Ecology (since 2007)
- Review of the Research Centre for The Safety of The Coal Industry (East) (from 2016)
Teaching and organizational activities in domestic and foreign universities
- 1978-1979 Visiting researcher at Rice University. Research subjects - nanoscale particles in the structure of zeoliths, dehydroaromatization (Houston, Texas, USA)
- 1977-1989 Associate Professor of Physical Chemistry at Novosibirsk State University
- 1979 - 1982 First Deputy Dean of the Faculty of Natural Sciences of Novosibirsk State University
- 1992, 1994 Visiting Professor (NATO) at Louis Pasteur University (Strasbourg, France)
- 1993 Visiting Professor at Northwestern University and Pacific Northwest National Laboratory (PNNL, Richland, Washington, USA)
- 2008, 2010 - Lecture scan for graduate students at the University of Them. Al-Farabi (Almaty, Kazakhstan)
- 2011- head of the Department of Coal Chemistry, Plastics and Environmental Engineering at Kuzbass State Technical University. T.F. Gorbachev.
Invited opponent on dissertations and participation in the dissertation boards of several foreign universities (Utrecht, Twente, Turku, Oulu, Al-Ain).
Managing international projects - 9 projects of the International Science and Technology Center, INTC
- 7 projects of the Netherlands Foundation for the Advancement of Science, NWO, Netherlands
- Contract No. 6600028821 with Saudi Aramco. "Oxidizing depletion of liquid fuels"
- Project 7of Framework European Program - DEMCAMER - "Design and production of catalytic membrane reactors by developing new nanostructured catalytic and selective membrane materials"
- 2 COPERNICUS projects,
- 4 INTAS projects,
- 3 projects of the Japan Energy development and development fund, NEDO
- More than 15 integration projects of THE RAS, SB RAS with academies of sciences of Azerbaijan, Belarus, Kazakhstan and Ukraine.
- He is currently the head of a major joint project on carbon chemistry with the Institute of Coal Chemistry of the Chinese Academy of Sciences, Taiyuan.
International recognition
He is a member and chairman of the organizing committees and participates in many international conferences.
Reports at the International Congresses on Catalism:
- Tokyo (1980), Calgary (1988), Budapest (1992), Baltimore (1996), Granada (2000), Paris (2004), Seoul (2008); Munich (2012); Beijing (2016);
At the European Congresses on Catalism: - Maastricht (1995), Krakow (1997), Rimini (1999), Limerick (2001), Innsbruck (2003), Sofia (2005), Turku (2007), Salamanca (2009); Glasgow (2011), Lyon (2013); Kazan (2015), Florence (2017), Aachen (2019);
At the International and European Congresses on Ecological Catalysis: - Pisa (1995), Miami (1998), Majori (2001);
- Annual World Conference on Carbon, Krakow (2012), Jeju (2014);
- Annual International Pittsburgh Coal Conference, Istanbul (2010), Beijing (2013);
- International Symposium on Carbon for Catalysis (CarboCat), Lausanne (2004), St. Petersburg (2006), Berlin (2008), Dalian (2010), Brixen (2012), Trondheim (2014), Strasbourg (2016), Porto (2018);
- International Workshops on Catalytic Combustion, San Diego (1999), Seoul (2002), Ischia (2005), zurich (2008);
- International Conference on Environmental Catalysis Miami (1998), Beijing (2010), Lyon (2012);
- Russian Congress on Catalysis ROSCATALIS, Moscow (2011), Samara (2014), Nizhny Novgorod (2017);
- Mendeleev Congress on General and Applied Chemistry, St. Petersburg (1998), Kazan (2003), Moscow (2007), Volgograd (2011), Yekaterinburg (2016);
Participation in the examination of projects and scientific activities of leading Western scientists.
Lectures at leading Western universities, U.S. National Laboratories and Industrial Companies Research Centers, about 50.
Guest Lecturer at the Opening Ceremony of the European Society of Materials (EMRS), France (2015).
Literature and Awards
- 1999 - Distinguished Scientist of Science of the Russian Federation
- 2005 - Winner of the V.A. Koptyuga Prize
- 1999, 2007, 2017 - Honours of the Presidency of the Russian Academy of Sciences
- 1993, 2017 Honours of the Presidency of the SB RAS
- 2008 - Thanks to the Governor of Novosibirsk Region
- 1995, 2000 - VVC Medals
- 1997 - Eureka Exhibition Medal, Brussels
- 2007- Medal by them. Academician V.P. Makeeva, Federation of Cosmonautics
- 2012 - Order of Honour Of Kuzbass
- 2013 - 70 years of Kemerovo region medal
- 2016 - Honorary Member of the Academy of Sciences of the Republic of Tatarstan
- 2017 - Emeritus Professor Kuzbass
- 2017 - medal 60 years of SB RAS
- 2017 - FANO Honours
- Numerous certificates of the RCO to them D.I. Mendeleev.
Training in project management
U.S. Department of Commerce Special Program (SABIT) Long Internship and Training Organization for Science and Management, March-May 2003, Richland, Washington, USA.
Small Business Training, Market Relations and Technology Parks, October - November 2006, University of Arizona, Tucson, Livermore National Laboratory, Livermore, USA.
Training of scientific staff and publications
Ismagilov is active in training scientific personnel, among his students 6 doctors and 29 PhDs, is a scientific consultant of 2 doctoral students, scientific director of six graduate students and PhD candidates.
The bibliographic list of ismagilov's scientific publications with co-authors contains more than 1500 titles (gsNTB data).
On the basis of WoS: 356 articles, quoting 3860, Hirsch index 29 and including after being elected a member-correspondent of the RAS in 2011. 170 articles and 43 patents.
On the basis of RINK: 1200 articles, citations 7930, Hirsch index 37.
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